Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties
Journal
Chemical Communications
Journal Volume
47
Journal Issue
30
Pages
8694-8696
Date Issued
2011
Author(s)
Abstract
Reaction of [Ru(II)(PPh(3))(3)Cl(2)] with HQ and KCN produces a new dicyanoruthenium(III) building block, [Ru(III)(Q)(2)(CN)(2)](-). It reacts with hydrated CoCl(2) in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.
Type
journal article