Stereocontrolled functionalization of acyclic molybdenum-η3- allyl complexes: A new approach to the stereoselective synthesis of 1,3-diols
Journal
Journal of the Chemical Society, Chemical Communications
Journal Issue
18
Pages
1285-1287
Date Issued
1990
Author(s)
Abstract
Functionalization of [CpMo(CO)2(η3-syn-1-C3H4COCH3)] proceeds in a highly stereospecific manner; the Mo-η3-allyl unit is effective in directing asymmetric carbon induction in the course of s-trans-η4-cis-pentadiene formation, aldol condensation and asymmetric 1,3-diol synthesis.
Type
journal article