Influences of dielectric constant and scan rate on hysteresis effect in perovskite solar cell with simulation and experimental analyses
Journal
Scientific Reports
Journal Volume
12
Journal Issue
1
Date Issued
2022-12-01
Author(s)
Abstract
In this work, perovskite solar cells (PSCs) with different transport layers were fabricated to understand the hysteresis phenomenon under a series of scan rates. The experimental results show that the hysteresis phenomenon would be affected by the dielectric constant of transport layers and scan rate significantly. To explain this, a modified Poisson and drift-diffusion solver coupled with a fully time-dependent ion migration model is developed to analyze how the ion migration affects the performance and hysteresis of PSCs. The modeling results show that the most crucial factor in the hysteresis behavior is the built-in electric field of the perovskite. The non-linear hysteresis curves are demonstrated under different scan rates, and the mechanism of the hysteresis behavior is explained. Additionally, other factors contributing to the degree of hysteresis are determined to be the degree of degradation in the perovskite material, the quality of the perovskite crystal, and the materials of the transport layer, which corresponds to the total ion density, carrier lifetime of perovskite, and the dielectric constant of the transport layer, respectively. Finally, it was found that the dielectric constant of the transport layer is a key factor affecting hysteresis in perovskite solar cells.
Subjects
ION MIGRATION; ANOMALOUS HYSTERESIS; HIGH-EFFICIENCY; V HYSTERESIS; TRANSPORT; IMPACT; RECOMBINATION; POLARIZATION; ABSORBER; MOBILITY
Publisher
NATURE PORTFOLIO
Type
journal article