Using host-guest complexation to fold a flexible linear organic string: Kinetically controlled syntheses of [3]catenanes and a five-membered molecular necklace
Journal
Angewandte Chemie - International Edition
Journal Volume
51
Journal Issue
40
Pages
10094-10098
Date Issued
2012
Author(s)
Abstract
Rings and necklaces: Three [3]catenanes and a five-membered molecular necklace ([5]MN), with up to 60- and 92-membered rings as their centerpieces, respectively, have been synthesized. The synthesis started from the corresponding complexes in which the threaded flexible linear guests were bent at approximately right angles to facilitate kinetically controlled macrocyclizations. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
SDGs
Type
journal article