Scanning tunneling microscopy/spectroscopy of picene thin films formed on Ag(111)
Journal
Journal of Chemical Physics
Journal Volume
141
Journal Issue
11
Date Issued
2014
Author(s)
Yoshida, Yasuo
Yang, Hung-Hsiang
Huang, Hsu-Sheng
Guan, Shu-You
Yanagisawa, Susumu
Yokosuka, Takuya
Su, Wei-Bin
Chang, Chia-Seng
Hoffmann, Germar
Hasegawa, Yukio
Abstract
Using ultrahigh-vacuum low-temperature scanning tunneling microscopy and spectroscopy combined with first principles density functional theory calculations, we have investigated structural and electronic properties of pristine and potassium (K)-deposited picene thin films formed in situ on a Ag(111) substrate. At low coverages, the molecules are uniformly distributed with the long axis aligned along the [112̄] direction of the substrate. At higher coverages, ordered structures composed of monolayer molecules are observed, one of which is a monolayer with tilted and flat-lying molecules resembling a (11̄0) plane of the bulk crystalline picene. Between the molecules and the substrate, the van der Waals interaction is dominant with negligible hybridization between their electronic states; a conclusion that contrasts with the chemisorption exhibited by pentacene molecules on the same substrate. We also observed a monolayer picene thin film in which all molecules were standing to form an intermolecular π stacking. Two-dimensional delocalized electronic states are found on the K-deposited π stacking structure.
Type
journal article