Synthesis and properties of chitosan-modified poly(vinyl acetate)
Journal
Journal of Applied Polymer Science
Journal Volume
86
Journal Issue
12
Pages
3057-3063
Date Issued
2002
Author(s)
Abstract
Abstract A redox initiator, cerium ammonium nitrate, was used to initiate the graft copolymerization of vinyl acetate (VAc) onto the chitosan chain in a dispersion polymerization at 60°C. With an addition of 0.5–7.5 g of chitosan based on 50 g of VAc, the monomer conversion was found to be between 70 and 80% after 2 h of reaction. The grafting efficiency increased with the amount of chitosan added; yet, the grafting ratio increased slightly and then decreased. After the reaction, a stable dispersion system was observed and the surface of the latex particles was found to be rich in chitosan. All the experimental results indicated that the chitosan molecules not only took part in the graft copolymerization, but also served as a surfactant, providing the stability of the dispersion particles. If the dispersion aqueous solution was oven‐dried, a particulate membrane was formed. The experimental results indicated that the incorporation of poly(vinyl acetate) to the chitosan chains increased the toughness and decreased the water absorption of the chitosan material. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3057–3063, 2002
Abstract A redox initiator, cerium ammonium nitrate, was used to initiate the graft copolymerization of vinyl acetate (VAc) onto the chitosan chain in a dispersion polymerization at 60°C. With an addition of 0.5–7.5 g of chitosan based on 50 g of VAc, the monomer conversion was found to be between 70 and 80% after 2 h of reaction. The grafting efficiency increased with the amount of chitosan added; yet, the grafting ratio increased slightly and then decreased. After the reaction, a stable dispersion system was observed and the surface of the latex particles was found to be rich in chitosan. All the experimental results indicated that the chitosan molecules not only took part in the graft copolymerization, but also served as a surfactant, providing the stability of the dispersion particles. If the dispersion aqueous solution was oven‐dried, a particulate membrane was formed. The experimental results indicated that the incorporation of poly(vinyl acetate) to the chitosan chains increased the toughness and decreased the water absorption of the chitosan material. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3057–3063, 2002
SDGs
Type
journal article