A carbazole-phenylbenzimidazole hybrid bipolar universal host for high efficiency RGB and white PhOLEDs with high chromatic stability
Journal
Journal of Materials Chemistry
Journal Volume
21
Journal Issue
48
Pages
19249-19256
Date Issued
2011
Author(s)
Abstract
A novel bipolar molecule CNBzIm comprised of electron-donating carbazole and electron-accepting phenylbenzimidazole is designed, synthesized and characterized for RGB phosphorescent organic light emitting diodes (PhOLEDs). CNBzIm exhibits promising properties such as high triplet energy (ET = 2.71 eV) due to disrupted π-conjugation, bipolar and balanced charge transport ability (μh ≈ μe ≈ 10−5 cm2 V−1s−1), and high morphological stability (Tg = 185 °C). PhOLEDs adopted CNBzIm as a host respectively doped with Os(bpftz)2(PPh2Me)2, (PPy)2Ir(acac) and FIrpic under the same device structure show excellent performance with external quantum efficiencies (ηext) as high as 19.1% for red, 17.8% for green, and 12.7% for blue. A two-color, all-phosphor and single-emitting-layer WOLED hosted by CNBzIm was achieved with a maximum ηext of 15.7%, current efficiency (ηc) of 35 cd A−1, and power efficiency (ηp) of 36.6 lm W−1. Utilizing a bipolar host with balanced mobilities, WOLED can effectively broaden its recombination zone and show high color stability. The Commission Internationale de L'Eclairage (CIE) coordinates of the WOLED remain almost constant when the brightness goes from 1700 cd m−2 (0.32, 0.41) to 49 900 cd m−2 (0.31, 0.41).
SDGs
Type
journal article