Design of reverse osmosis membranes for molecular separation: Size-exclusion vs. Adsorption-facilitation mechanisms
Journal
Separation and Purification Technology
Journal Volume
364
Start Page
132269
ISSN
1383-5866
Date Issued
2025-08-30
Author(s)
Yen-Yung Wu
Abstract
Reverse osmosis (RO) is a key technology to various separation applications, whose processes traditionally rely on the well-known size-exclusion mechanism to block the greater component in size. Interestingly, recent studies have also demonstrated RO processes that can selectively permeate larger molecules via their favorable adsorption. While these distinct behaviors have been observed, a comprehensive understanding on the design of RO membranes remains lacking. To this end, by employing molecular dynamics simulations, this study conducts a systematic evaluation on RO membranes with different pore dimensions for their separation performance of a binary mixture comprising components of varying molecular sizes, offering quantitative insights into the design of RO membranes. The outcomes show that, while the traditional size-exclusion design remains an effective approach, utilizing the adsorption-facilitated mechanism may lead to a notably enhanced performance with rich separation behaviors. Specifically, the pore size may be designed to be greater than both of the components for a boosted permeation flux. Moreover, through strategically exploiting the confinement effect for preferentially adsorbing a specific component, either the smaller or the greater one, effective RO processes to selectively permeate the either component can be achieved.
Subjects
Adsorption-facilitated separation
Membrane design
Molecular dynamics simulation
Reverse osmosis
Size exclusion
Publisher
Elsevier BV
Type
journal article