A machine learning model for estimating daily maximum 8-hour average ozone concentrations using OMI and MODIS products
Journal
Atmospheric Environment
Journal Volume
331
Start Page
120587
ISSN
1352-2310
Date Issued
2024-08-15
Author(s)
DOI
10.1016/j.atmosenv.2024.120587
Abstract
Tropospheric ozone (O3) is a criteria air pollutants posing risks to organisms, and is expected to enhance formation due to climate change. Satellite-based measurements provide a promising approach to estimate ground-level air pollution on large scale. However, most applications of satellite-based measurements have been used for fine particulate matter and nitrogen dioxide, while only a few have been used for O3. In this study, we incorporated satellite-based measurements from the Ozone Monitoring Instrument (OMI) and MOderate-resolution Imaging Spectroradiometer (MODIS) with meteorological variables and land-use data to estimate daily maximum 8-h average O3 at 1-km resolution in Taiwan during 2004–2020. The random forest model was used to impute the missing values of the satellite-based measurements. Additionally, the XGBoost model was leveraged to estimate daily O3 concentrations. Model performance was evaluated by the ten-fold cross-validation (CV), temporal and spatial validation, and the results were reported as the coefficient of determination (R2) and root mean square error (RMSE). Our results showed that the 10-fold CV, temporal validated, and spatial validated R2 (RMSE) of the XGBoost model were 0.82 (7.71 ppb), 0.63 (11.09 ppb), and 0.68 (10.27 ppb), respectively. Our model performance was better in central and southern Taiwan. The top ten important predictors were date (relative importance = 12.15%), temperature (10.77%), meridional wind (10.71%), relative humidity (9.60%), zonal wind (8.14%), UV radiation (8.07%), total precipitation (6.35%), surface pressure (5.34%), surface O3 volume mixing ratio (4.93%), and boundary layer height (4.69%). The spatial distribution of O3 estimates showed that daily maximum 8-h average O3 concentrations were higher in the suburban and mountainous areas near the central and southern Taiwan. This reveals that sensitive populations should still pay attention to the secondary pollutants even when outside the urban areas. The O3 estimates can be further leveraged to evaluate the short-term and long-term effects of O3 on human health.
Subjects
Aerosol optical depth
Daily maximum 8-h ozone
Extreme gradient boosting model
OMI O3
Remote sensing
Spatiotemporal estimation model
Publisher
Elsevier BV
Type
journal article