Directing self-assembly in macromolecular systems: Hydrogen bonding in ordered polymers
Journal
Pure and Applied Chemistry
Journal Volume
76
Journal Issue
7-8
Pages
1337
Date Issued
2004-01-01
Author(s)
Li, Xuefa
Abstract
Hydrogen-bonded side-chain liquid-crystalline block copolymers (SCLCBCPs) containing block segments with proton donors were combined with functionalized mesogenic pendent groups. Studies of a wide range of mesogen and polymer combinations were carried out to study the relationship between morphology and mesophase behavior. The thermal behaviors of the resulting self-assembled microstructures were also examined. A model of the assembly process leading to mesogenic group organization corresponding to different compositions was proposed.
Type
conference paper
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