Impact of HCl and O2 on removal of elemental mercury by heat-treated activated carbon: Integrated X-ray analysis
Journal
Fuel Processing Technology
Journal Volume
167
Pages
11-17
Date Issued
2017
Author(s)
Abstract
Treated activated carbons, prepared by heat treatment of activated carbon sorbents under the protection of argon (Ar), were subjected to synthetic flue gases to investigate its elemental mercury (Hg0) capture and the specific role of HCl and O2. To elucidate the adsorption mechanisms & binding properties, subsequent sorbents were characterized by X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy. The results suggest that Hg0 capture on the heat treated activated carbon (TAC) under HCl atmosphere mainly follows Eley-Rideal reaction mechanism, where, HCl reacts with the basic active carbon sites on the TAC leading to the formation of Cl-containing active sites, subsequently gaseous Hg0 heterogeneously reacts with these Cl-containing active sites through electron-transfer and forms HgClx compounds. Both the 2.42 Å and 2.39 Å bonding distance of Hg-Cl shows that only one of the two valence electrons on mercury bond with Cl, while the other electron bonds with the basic active carbon site covalently. In presence of HCl and O2, the synergistic effect of O2 on Hg0 adsorption might attribute to the O2 adsorption and the subsequent formation of oxygen-containing functional groups (OFGs) on TAC, which increase the amount of effective activated sites for Hg0 adsorption and at the same time enhance the adsorbing kinetics of adjacent Cl-containing sites.
SDGs
Type
journal article