Precise Facial Control in Threading Guests into a Molecular Cage and the Formation of a Turtlelike Supramolecular Complex
Resource
Angewandte Chemie International Edition 45 (19): 3176-3181
Journal
Angewandte Chemie International Edition
Journal Volume
45
Journal Issue
19
Pages
3176-3181
Date Issued
2006
Date
2006
Author(s)
Abstract
Caught in a cage: Two different thread components and a molecular cage generate different [2]pseudorotaxane-like complexes, which represent a new type of molecular machinery. An unprecedented type of molecular motion is generated by the addition of K+ ions and [2,2,2]cryptand units to this mixture and their removal from it, in which the rodlike components penetrate the molecular cage alternately through its different faces.
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Type
journal article
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