Synthesis and crystal structure of maleonitriledithiolate metal complexes with N-methylacridine as cations
Journal
Polyhedron
Journal Volume
22
Journal Issue
28
Pages
3547-3553
Date Issued
2003
Author(s)
Abstract
The synthesis of [N-MeA]2[M(mnt)2] (N-MeA = N-methylacridine; M = Ni (II), Zn (II), Cu (II) and Cd (II); mnt = maleonitriledithiolate) and crystal structure analysis of the Ni (1) and Zn (2) complexes are reported. The conductivities of almost all the complexes under 4 MPa pressure are above 10-5 S cm-1, which are characteristic of intrinsic semi-conductors. The complexes exhibit charge transfer transitions in both their absorption spectra and fluorescence spectroscopy. © 2003 Elsevier Ltd. All rights reserved.
Type
journal article