The synthesis of the fully conjugated of extended bimetal-porphyrin and application
Date Issued
2007
Date
2007
Author(s)
Lin, Rong-Shin
DOI
zh-TW
Abstract
To synthesize a conjugation system of porphyrins and to study their properties with metal ions are the major work of this thesis. With the assists of microwave technology, the target molecule was easily achieved. In the presence of the diketone porphyrin with 5,6-diamino-1,l0-phenanthroline in a co-solvent system (CH2Cl2:Et2O: MeOH:H2O) proceeded smoothly to yield the p-diketoone prophyrin (A9). Complexation of A9 with various metal ions were investigated. In a typical example, reaction of CoCl2 with A9 in the DMF, produced a metal-prophyrin species C1. This cobalt prophyrin complex can be used as a catalyst in oxidation olefin, benzaldehydes and sulfides under mild conditions.
Subjects
雙酮紫質
雙金屬
porphyrin
Type
thesis
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