Development of a fluorous, oxime-based palladacycle for microwave-promoted carbon-carbon coupling reactions in aqueous media
Journal
Green Chemistry
Journal Volume
14
Journal Issue
1
Pages
77-80
Date Issued
2012
Author(s)
Abstract
A thermally stable, fluorous oxime-based palladacycle has been developed and was shown to efficiently promote various carbon–carbon bond formation reactions (Suzuki–Miyaura, Sonogashira and Stille) in aqueous media under microwave irradiation. The palladacycle gave extremely low levels of Pd leaching and could be reused five times with no significant loss of activity.
Type
journal article