Forced Spreading of Aqueous Solutions on Zwitterionic Sulfobetaine Surfaces for Rapid Evaporation and Solute Separation
Journal
Langmuir
Journal Volume
33
Journal Issue
30
Pages
7569-7574
Date Issued
2017
Author(s)
Abstract
Solute separation of aqueous mixtures is mainly dominated by water vaporization. The evaporation rate of an aqueous drop grows with increasing the liquid-gas interfacial area. The spontaneous spreading behavior of a water droplet on a total wetting surface provides huge liquid-gas interfacial area per unit volume; however, it is halted by the self-pinning phenomenon upon addition of nonvolatile solutes. In this work, it is shown that the solute-induced self-pinning can be overcome by gravity, leading to anisotropic spreading much faster than isotropic spreading. The evaporation rate of anisotropic spreading on a zwitterionic sulfobetaine surface is 25 times larger as that on a poly(methyl methacrylate) surface. Dramatic enhancement of evaporation is demonstrated by simultaneous formation of fog atop liquid film. During anisotropic spreading, the solutes are quickly precipitated out within 30 s, showing the rapid solute-water separation. After repeated spreading process for the dye-containing solution, the mean concentration of the collection is doubled, revealing the concentration efficiency as high as 100%. Gravity-enhanced spreading on total wetting surfaces at room temperature is easy to scale-up with less energy consumption, and thus it has great potentials for the applications of solute separation and concentration. © 2017 American Chemical Society.
SDGs
Other Subjects
Anisotropy; Energy utilization; Esters; Evaporation; Liquefied gases; Liquid films; Liquids; Separation; Solutions; Aqueous mixtures; Evaporation rate; Interfacial areas; Mean concentrations; Non-volatile solute; Simultaneous formation; Water vaporization; Zwitterionic sulfobetaine; Wetting
Type
journal article