π-face differentiation in Michael reaction to the enone group adjacent to the (η-C5H5)Mo(CO)2(π-allyl) fragment: A new approach to the stereoselective synthesis of 2,3,4,5-tetrasubstituted-tetrahydrofuran compounds
Journal
Journal of the Chemical Society, Chemical Communications
Journal Issue
18
Pages
1391-1393
Date Issued
1993
Author(s)
Abstract
The stereochemical outcome of the 1,4-addition of organocopper reagents to (η-C5H5)Mo(CO)2[η3-1-(E)- C3H4COCH=CHR] compounds has been elucidated; utilization of this reaction for synthesis of 2,3,4,5-tetrasubstituted tetrahydrofuran is demonstrated.
SDGs
Type
journal article