Preparation and characterization of hyperbranched polyaspartimides from bismaleimides and triamines
Journal
Journal of Polymer Science, Part A: Polymer Chemistry
Journal Volume
42
Journal Issue
23
Pages
5921-5928
Date Issued
2004
Author(s)
Abstract
Abstract Hyperbranched polyaspartimides were successfully prepared from bismaleimides ( A 2 ) and triamines ( B 3 ) through the Michael addition reaction. Two bismaleimides of 4,4′‐bismaleimidodiphenylmethane (BMDM) and bis(3‐ethyl‐5‐methyl‐4‐ maleimidophenyl)methane (BEMM) and two triamines of tris(3‐aminophenyl)phosphine oxide (TAPPO) and tris(4‐aminophenyl)amine (TAPA) were employed in the preparation of these hyperbranched polyaspartimides. The chemical structures of the polymers were characterized with Fourier transform infrared (FTIR), 1 H and 31 P NMR, and elemental analysis. Degrees of branching ranging from 0.51 to 0.69 were found with the polyaspartimides, ensuring their hyperbranched structure. The polymers also showed good solubility in common solvents, high glass‐transition temperatures of 256 °C, and excellent thermal stability above 370 °C. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5921–5928, 2004
Type
journal article