Synthesis, characterisation and reactivity of novel bis(tosyl)imidoruthenium(vi) porphyrin complexes; X-ray crystal structure of a tosylamidoruthenium(iv) porphyrin
Resource
Chemical Communications 1997: 1655-1656
Journal
Chemical Communications
Journal Issue
17
Pages
1655-1656
Date Issued
1997
Date
1997
Author(s)
Abstract
Bis(tosyl)imidoruthenium(VI) porphyrin complexes are prepared and characterised by spectroscopic means; [Ru VI - (tpp)(NTs) 2 ] can undergo imido group transfer reactions with alkenes to afford aziridines, as well as C–H bond oxidation of benzyl alcohol to give benzaldehyde; a tosylamido ruthenium(IV) complex is also isolated and characterised by X-ray diffraction.
Type
journal article
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