Quantifying the impacts of PM2.5 constituents and relative humidity on visibility impairment in a suburban area of eastern Asia using long-term in-situ measurements
Journal
Science of the Total Environment
Date Issued
2021
Author(s)
Abstract
The deterioration of visibility due to air pollutants and relative humidity has been a serious environmental problem in eastern Asia. In most previous studies, chemical compositions of atmospheric particles were provided using filter-based offline analyses, which were unable to provide long-term and in-situ measurements that resolve sufficient temporal variations of air pollution and meteorology, hindering the resolution of the relationship between air quality and visibility. Here, we present a year-long continuously measured data from a comprehensive suite of online instruments to investigate diurnal and seasonal impacts of the aerosol chemical compositions in PM2.5 on visibility seasonally and diurnally. The measured dry aerosol extinction at λ = 550 nm reached a closure with that predicted by aerosol compositions within 12%. However, the hygroscopic growth of particles under ambient RH could enhance the aerosol extinction by a factor of 2–6, matching the perceptive visibility of the public. Particulate ammonium nitrate was most sensitive to reducing visibility, while ammonium sulfate contributed the most to the light extinction. In spring and winter, the monsoon and stagnant air masses reduced the visibility and increased PM2.5 (>35 μg m?3). The moisture was found to substantially enhance the light extinction under RH = 60–90%, reducing visibility by approximately 15 km, largely attributed to hygroscopic inorganic salts. This study serves as a metric to highlight the need to consider the influence of RH, and aqueous reactions in producing secondary inorganic aerosols on atmospheric visibility, underpinning the more accurate mitigation strategies of air pollution. ? 2021 Elsevier B.V.
Subjects
Hygroscopic aerosols
In-situ measurements
Light extinction
Mitigation strategies
Relative humidity
Visibility
Aerosols
Air quality
Atmospheric chemistry
Atmospheric humidity
Chemical analysis
Deterioration
Nitrogen compounds
Sulfur compounds
Aerosol extinction
Air pollutants
Chemical compositions
Environmental problems
Hygroscopic aerosol
In-situ measurement
Mitigation strategy
PM 2.5
Suburban areas
Visibility impairment
Type
journal article