Octanuclear gold(i) alkynyl-diphosphine clusters showing thermochromic luminescence
Journal
Chemical Communications
Journal Volume
47
Journal Issue
19
Pages
5533-5535
Date Issued
2011
Author(s)
Abstract
The unprecedented, purely gold(I) alkynyl-diphosphine clusters 1-3 demonstrate intense room-temperature phosphorescence with maximum quantum efficiency of 92% in solution (3) and 86% in solid (2) and thermally dependent emission in the crystalline form, attributed to the crystal lattice arrangement.
Type
journal article