Perfluoro anion based binary and ternary ionic liquids as electrolytes for dye-sensitized solar cells
Journal
Journal of Power Sources
Journal Volume
311
Pages
167-174
Date Issued
2016
Author(s)
Abstract
In this work, eight new ionic liquids (ILs) based on triethylammonium (TEA) or n-methylpiperidinium (NMP) cations and perfluoro carboxylate (PFC) anions having different carbon chain lengths are synthesized and their physico-chemical properties such as density, decomposition temperature, viscosity and conductivity are determined. Photovoltaic characteristics of dye-sensitized solar cells (DSSCs) with binary ionic liquids electrolytes, containing the mixture of the synthesized ILs and 1-methyl-3-propyl imidazolium iodide (PMII) (v/v = 35/65), are evaluated. Among the different ILs, solar cells containing NMP based ILs show higher VOC than that of TEA, whereas, higher JSC is noted for the DSSCs incorporated with the latter when compared to the former. Further, the photo-current of the DSSCs decreases with the increase of the carbon chain length of perfluoro carboxylate anionic group of ILs. The cell performance of the DSSC containing ternary ionic liquids-based electrolytes compose of NMP-2C/TEA-2C/PMII (v/v/v = 28/7/65) exhibits a JSC of 12.99 mA cm-2, a VOC of 639.0 mV, a FF of 0.72, and a cell efficiency of 6.01%. The extraordinary durability of the DSSC containing the above combination of electrolytes stored in dark at 50 ¢XC is proved to be unfailing up to 1200 h. ? 2016 Elsevier B.V. All rights reserved.
Subjects
Dye-sensitized solar cell
Gel electrolytes
Ionic liquid
Long-term stability
Perfluoro carboxylate
SDGs
Other Subjects
Bins; Carboxylation; Chain length; Chains; Density of liquids; Dyes; Electrolytes; Ionic liquids; Liquids; Negative ions; Solar cells; Solar power generation; Solid electrolytes; Binary ionic liquids; Decomposition temperature; Gel electrolyte; Imidazolium iodides; Long term stability; Perfluoro carboxylate; Photovoltaic characteristics; Physicochemical property; Dye-sensitized solar cells
Type
journal article