Nanoarchitecture through Strained Molecules: Cubane-Derived Scaffolds and the Smallest Carbon Nanothreads
Journal
Journal of the American Chemical Society
Journal Volume
142
Journal Issue
42
Start Page
17944
End Page
17955
ISSN
00027863
Date Issued
2020
Author(s)
Zhu, Li
Ward, Matthew D.
Wang, Tao
Chen, Bo
Chaloux, Brian L.
Wang, Qianqian
Biswas, Arani
Gray, Jennifer L.
Kuei, Brooke
Cody, George D.
Epshteyn, Albert
Crespi, Vincent H.
Badding, John V.
Strobel, Timothy A.
Abstract
Relative to the rich library of small-molecule organics, few examples of ordered extended (i.e., nonmolecular) hydrocarbon networks are known. In particular, sp3 bonded, diamond-like materials represent appealing targets because of their desirable mechanical, thermal, and optical properties. While many covalent organic frameworks (COFs) - extended, covalently bonded, and porous structures - have been realized through molecular architecture with exceptional control, the design and synthesis of dense, covalent extended solids has been a longstanding challenge. Here we report the preparation of a sp3-bonded, low-dimensional hydrocarbon synthesized via high-pressure, solid-state diradical polymerization of cubane (C8H8), which is a saturated, but immensely strained, cage-like molecule. Experimental measurements show that the obtained product is crystalline with three-dimensional order that appears to largely preserve the basic structural topology of the cubane molecular precursor and exhibits high hardness (comparable to fused quartz) and thermal stability up to 300 °C. Among the plausible theoretical candidate structures, one-dimensional carbon scaffolds comprising six- and four-membered rings that pack within a pseudosquare lattice provide the best agreement with experimental data. These diamond-like molecular rods with extraordinarily small thickness are among the smallest members in the carbon nanothread family, and calculations indicate one of the stiffest one-dimensional systems known. These results present opportunities for the synthesis of purely sp3-bonded extended solids formed through the strain release of saturated molecules, as opposed to only unsaturated precursors. ©
Publisher
American Chemical Society
Type
journal article