Conductance and Stochastic Switching of Ligand-Supported Linear Chains of Metal Atoms
Resource
Angewandte Chemie International Edition 45 (35): 5814-5818
Journal
Angewandte Chemie International Edition
Journal Volume
45
Journal Issue
35
Pages
5814-5818
Date Issued
2006
Date
2006
Author(s)
Chen, I-Wen Peter
Fu, Ming-Dung
Tseng, Wei-Hsiang
Yu, Jian-Yuan
Wu, Sung-Hsun
Ku, Chia-Jui
Abstract
An alternative string theory: The current-versus-potential behavior of metal atom strings (Ni, Co, Cr) is dependent on the strength of the d-orbital coupling along the metal atom chain. Penta- and heptachromium strings each exhibit two sets of primary I–V curves, which depend on whether the CrCr bonds alternate and are localized, or are delocalized (see picture).
Type
journal article
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