Mechanochromic and vapochromic fluorescence of a bulky π-system: Alkyl chain-length effects, triplex emission, and differential sensing of aniline vapors
Journal
Journal of the Chinese Chemical Society
Pages
-
Date Issued
2020
Author(s)
Abstract
Abstract The interplay of mechanical grinding and aniline vapor fuming on the fluorescence of the pentiptycene‐anthracene‐pentiptycene π‐conjugated molecules PAP‐C n , where n is 4, 8, 12, or 16 and refers to the number of carbon atom in the terminal alkyl chains, in solid films are reported. The differences and similarities among the four homologs have led to a conclusion of the formation of an emissive triplex state for the ground and fumed films. Thermogravimetric analysis reveals the guest‐host molar ratio and the retention ability of the aniline on the various types of films. A stepwise protocol of fuming‐grinding‐annealing is developed for fluorimetric differential sensing of eight substituted aniline vapors with a single probe of PAP‐C8. The role of the bulky pentiptycene groups in the observed fluorescence properties is also discussed.
Type
journal article