Highly-efficient Ru/Al-SBA-15 catalysts with strong Lewis acid sites for the water-assisted hydrogenation of: P -phthalic acid
Journal
Catalysis Science and Technology
Journal Volume
10
Journal Issue
8
Pages
2443-2451
Date Issued
2020
Author(s)
Abstract
Ruthenium nanoparticles supported onto aluminum-doped mesoporous silica catalysts (Ru/Al-SBA-15) are fabricated using hydrothermal and impregnation methods for catalysis application. The Ru/Al-SBA-15-3 catalyst at a Si/Al molar ratio of 3 exhibited excellent catalytic performance for the hydrogenation of p-phthalic acid with high conversion efficiency (100.0%) and cis-isomer selectivity (84.0%) in water. Moreover, this system displays exceptional stability and recyclability through preserving the conversion efficiency, as well as a cis-isomer selectivity of 90.2 and 83.3%, respectively, after reusing it fourteen times. Such an exceptional system can also be ideal for the hydrogenation of aromatic dicarboxylic acids and their ester derivatives in water. Strong Lewis acid sites due to doped Al species play significant roles in the hydrogenation reaction. Moreover, isotope labeling studies indicated that water molecules effectively participated in the hydrogenation reaction. Hydrogen and water contributed half of the hydrogen atoms for this hydrogenation reaction. In the end, a plausible mechanistic pathway for the hydrogenation of p-phthalic acid using the Ru/Al-SBA-15-3 catalyst in water is proposed. This journal is ? The Royal Society of Chemistry.
Subjects
Atoms; Carboxylic acids; Catalyst selectivity; Conversion efficiency; Efficiency; Hydrogen; Isomers; Molar ratio; Molecules; Silica; Aromatic dicarboxylic acids; Catalytic performance; High conversion efficiency; Hydrogenation reactions; Impregnation methods; Isotope labeling studies; Mechanistic pathways; Ruthenium Nanoparticles; Hydrogenation
Type
journal article