Energy recovery from sewage sludge: Product characteristics, heating value prediction and reaction kinetics
Journal
Chemosphere
Journal Volume
268
Date Issued
2021
Author(s)
Abstract
Energy recovery from sewage sludge was carried out by using microwave and conventional torrefaction. The microwave torrefaction was carried out by using a laboratory-scale microwave oven that provides single-mode microwave irradiation at 2.45 GHz, and the amount of sewage sludge for each experiment was approximately 20 g. The efficiency of microwave heating can be substantially promoted at higher power level, resulting in higher heating rate and maximum temperature. According to higher energy yield and heating value of torrefied sewage sludge, the optimum power level for bioenergy produced by microwave torrefaction of sewage sludge should be 200 W. Because of lower mass yield and temperature required to obtain the same yield, microwave heating can be more effective than conventional heating for sewage sludge torrefaction. The elemental composition of torrefied sewage sludge at 400 W was similar to that of anthracite, and its low hydrogen and oxygen contents could prevent excessive formation of smoke. Two correlations were obtained to predict the HHV of SS based on proximate and elemental compositions. With the recovery of liquid and gas products as bioenergy, the energy return on investment for microwave torrefaction of sewage sludge can be up to 16.4, much higher than the minimum value required for a sustainable society. Because of lower activation energy but higher pre-exponential factor, microwave heating can be approximately five times faster than conventional heating. ? 2020 Elsevier Ltd
Subjects
Activation energy; Investments; Microwave heating; Reaction kinetics; Recovery; Sewage sludge; Smoke; Conventional heating; Elemental compositions; Energy return on investments; Maximum temperature; Preexponential factor; Product characteristics; Single-mode microwaves; Sustainable society; Microwave irradiation; ammonia; carbon; carbon dioxide; carbon monoxide; hydrogen; hydrogen cyanide; nitrogen; oxygen; anthracite; bioenergy; experimental study; heating; high temperature; microwave radiation; reaction kinetics; sewage; sludge; anaerobic digestion; bioenergy; chemical reaction kinetics; energy recovery; energy yield; gas; heating; kinetics; liquid; microwave irradiation; moisture; sewage; sewage treatment plant; sludge dewatering; thermogravimetry; heating; microwave radiation; temperature; Heating; Kinetics; Microwaves; Sewage; Temperature
SDGs
Type
journal article