Measurements for Thermodynamics and Kinetics of Methane Hydrate in the Presence of Acetamide, Cyclopentanol and 1,3-Dioxane
Date Issued
2014
Date
2014
Author(s)
Li, Li-Ting
Abstract
In this study, an apparatus which can be operated at low temperature and high pressure conditions was set up to measure the hydrate-liquid water-vapor (H-Lw-V) three-phase dissociation conditions of methane hydrate in the presence of additives by employing the isochoric method. The certain additives to system of methane + water were investigated for their effects on the phase boundary of methane hydrate. Also, the kinetic behavior of methane hydrate was investigated in an isochoric system to see how factors (e.g. sub-cooling temperature, experimental pressure) would affect the formation kinetics of methane hydrate.
In this work, acetamide, cyclopentanol and 1,3-dioxane were chosen as additives. The addition of acetamide in methane hydrate system shifted hydrate phase boundaries to higher pressure and lower temperatureand thus the hydrate stability region was broadened, therefore it had a inhibition effect on the formation of methane hydrate. Furthermore, the inhibition effect increased when the concentration of Acetamide in hydrate system increased. With 30 wt% acetamide the equilibrium temperature decreases about 8.7 K at given pressure in comparison to that of pure water system. On the other hand, the results of adding cyclopentanol or 1,3-dioxane showed the promotion effect on the formation of methane hydrate. Similarly, the promotion effect increased when the concentration of cyclopentanol or 1,3-dioxane in hydrate system increased. With 8 wt% cyclopentanol, the equilibrium temperature increases about 6.8 K at given pressure in comparison to that of pure water system. With 20 wt% 1,3-dioxane, the equilibrium temperature increases about 13.7 K at given pressure in comparison to that of pure water system. In addition, 3.5 wt% NaCl(aq) was usedas brine solution to simulate the salinity of the seawater environment. The dissociation conditions of methane hydrate in brine were also measured in this study with the addition of acetamide, cyclopentanol and 1,3-doxane.
In the formation kinetics of methane hydrate, 4-Hydroxy-4-methyl-2-pentanone (Diacetone Alcohol) was chosen as additive. The results showed that diacetone alcohol could reduce the induction time in comparison to that of pure water system and the initial rate of hydrate formation was effectively increased by adding diacetone alcohol. In conclusion, diacetone alcohol was an effective kinetic promoter to form methane hydrate in this work. In addition, cyclopentanol seems that it could shorten the induction time needed for hydrate formation so cyclopentanol was chosen as additive to test new formation kinetics experiments.
Subjects
甲烷水合物
熱力學相平衡
等容溫度循環法
水合物生成動力學
乙醯胺
環戊醇
1,3-二氧六環
二丙酮醇
Type
thesis
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