Structural, magnetic, and theoretical characterization of a heterometallic polypyridylamide complex
Journal
Angewandte Chemie - International Edition
Journal Volume
46
Journal Issue
19
Pages
3533-3536
Date Issued
2007
Author(s)
Rohmer, M.-M.
Liu, I.P.-C.
Lin, J.-C.
Chiu, M.-J.
Lee, C.-H.
Lee, G.-H.
Bénard, M.
López, X.
Abstract
A heterometallic backbone has been obtained for the first time in a trinuclear complex of bis(2-pyridyl)amide (dpa), namely, [Co2PdCl2(dpa)4] (1). The crystal structure (depicted), magnetic measurements, and DFT calculations suggest that its ground state results from coupling of two high-spin CoII ions separated by a magnetically inactive Pd center. Hence, the magnetic behavior of CoII in 1 strongly differs from that in its tricobalt homologue. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z604313_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Type
journal article