Conversion and Kinetics Study of Fructose-to-5-Hydroxymethylfurfural (HMF) Using Sulfonic and Ionic Liquid Groups Bi-functionalized Mesoporous Silica Nanoparticles as Recyclable Solid Catalysts in DMSO Systems.
Resource
Physical Chemistry Chemical Physics, 14(40), 13914-13917
Journal
Physical Chemistry Chemical Physics
Pages
13914
Date Issued
2012
Date
2012
Author(s)
Lee, Yin-Ying
Abstract
Mesoporous silica nanoparticles functionalized with both sulfonic acid (HSO(3)) and ionic liquid (ILs) were synthesized and applied as effective and recyclable catalysts for generating 5-hydroxymethylfurfural (HMF) from fructose. For the first time a high HMF yield of 72.5% was achieved in DMSO systems under mild conditions (90 °C and 3 h). We further studied the kinetics of the fructose-to-HMF conversion and compared the rate constants, reaction orders, and activation energies for the systems with and without bi-functional MSN catalysts.
SDGs
Type
journal article
File(s)![Thumbnail Image]()
Loading...
Name
19.pdf
Size
23.44 KB
Format
Adobe PDF
Checksum
(MD5):8817c71523cc28e88ba946fc7b6506db