Disinfection byproduct formation kinetics of a water treatment plant on Kinmen Island
Journal
Water Science and Technology: Water Supply
Journal Volume
15
Journal Issue
6
Pages
1200-1206
Date Issued
2015
Author(s)
Abstract
Chloramine has often been used as a chlorine alternative for trihalomethane (THM) and haloacetic acid (HAA) control. However, nitrogenous disinfection byproduct (N-DBP) formation and nitrification in distribution have always been major concerns in chloramination practices. On Kinmen Island, the high organic nitrogen content in raw water may increase the nitrogenous DBP formation. Simulated distribution system tests were conducted to explore the DBP formation kinetics in the distribution system. Lower haloacetonitrile (HAN4) formation (0.26 μg L-1) with chloramination than with chlorination (10.48 μg L-1) was observed from the 24 hours of reaction time. The nitrogen sources contributing to the dichloroacetonitrile (DCAN) formation kinetics were explored with 15Nchloramination. The results showed that nitrogen sourced from organic nitrogen was more dominant in DCAN formation with low chloramine dosage. This suggests that chloramine contributes to less DCAN formation in practice, especially for short distribution systems. In summary, the results provide evidence that simultaneous post-chloramination and pre-chlorination would be a feasible disinfection strategy applied to control regulated THM and HAA formation on Kinmen Island. © IWA Publishing 2015.
Subjects
Chloramine; Disinfection byproduct; Haloacetic acid; Haloacetonitrile; Simulated distribution system test; Trihalomethane
SDGs
Other Subjects
Amination; Chlorination; Kinetics; Local area networks; Nitrogen; Water distribution systems; Water pollution control; Water treatment; Chloramine; Disinfection by-product; Haloacetic acids; Haloacetonitrile; Simulated distribution systems; Trihalomethanes; Disinfection; chlorine; disinfectant agent; drinking water; nitrogen; organic nitrogen; phthalic acid dibutyl ester; tosylchloramide sodium; chemical compound; chemical reaction; disinfection; organic nitrogen; reaction kinetics; water treatment; Article; chlorination; disinfection; kinetics; reaction time; Taiwan; waste water treatment plant; water supply; water treatment; Quemoy; Taiwan
Type
journal article