Mathematical simulation of hydrogen production via methanol steam reforming using double-jacketed membrane reactor
Resource
International Journal of Hydrogen Energy 32 (18): 4830-4839
Journal
International Journal of Hydrogen Energy
Journal Volume
32
Journal Issue
18
Pages
4830-4839
Date Issued
2007
Date
2007
Author(s)
Fu, Chi-Hua
Abstract
The hydrogen production and purification via methanol reforming reaction was studied in a double-jacketed Pd membrane reactor using a 1-D, non-isothermal mathematical model. Both mass and heat transfer behavior were evaluated simultaneously in three parts of the reactor, annular side, permeation tube and the oxidation side. The simulation results exhibited that increasing the volumetric flow rate of hydrogen in permeation side could enhance hydrogen permeation rate across the membrane. The optimum velocity ratio between permeation and annular sides is 10. However, hydrogen removal could lower the temperature in the reformer. The hydrogen production rate increases as temperature increases at a given Damköhler number, but the methanol conversion and hydrogen recovery yield decrease. In addition, the optimum molar ratio of air and methanol was 1.3 with three air inlet temperatures. The performance of a double-jacketed membrane reactor was compared with an autothermal reactor by judging against methanol conversion, hydrogen recovery yield and production rate. Under the same reaction conditions, the double-jacketed reactor can convert more methanol at a given reactor volume than that of an autothermal reactor. © 2007 International Association for Hydrogen Energy.
SDGs
Other Subjects
Chemical reactors; Mathematical models; Methanol; Reforming reactions; Autothermal membrane reactor; Double-jacketed membrane reactor; Methanol steam reforming; Hydrogen production
Type
journal article
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