Catalytic and asymmetric aziridination of alkenes catalysed by a chiral manganese porphyrin complex
Resource
Chemical Communications 1997: 2373-2374
Journal
Chemical Communications
Journal Issue
24
Pages
2373-2374
Date Issued
1997
Author(s)
Abstract
A D4-manganese(III) porphyrin is utilized to catalyze aziridination of styrene-type substrates with enantiomeric excess ranging from 43 to 68%; evidence for a MnIV reactive intermediate in the catalysis was obtained from spectroscopic studies and organic product analysis.
SDGs
Type
journal article