X-ray Absorption Spectroscopic Studies on Light-Induced Excited Spin State Trapping of an Fe(II) Complex
Resource
Journal of the American Chemical Society 122 (24): 5742-5747
Journal
Journal of the American Chemical Society
Pages
5742-5747
Date Issued
2000
Date
2000
Author(s)
Lee, Jey-Jau
Sheu, Hwo-shuenn
Lee, Chi-Rung
Chen, Jin-Ming
Lee, Jyh-Fu
Wang, Chih-Chieh
Huang, Chun-Hsun
Wang, Yu
Abstract
Light-induced excited spin state trapping of Fe(phen)2(NCS)2 is studied by X-ray absorption spectroscopy using synchrotron radiation. The molecular structure of the excited high-spin state at 17 K is investigated by EXAFS. The relaxation of the light-induced high-spin state at various temperatures is monitored through the absorption spectra. The concurrent abrupt lattice change with the change in electronic configuration is observed through single crystal X-ray diffraction. The lattice cooperative effect is important in the relaxation behavior. The magnetic property and the relaxation behavior of two differently prepared samples are distinctly different.
Type
journal article
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