Preparation, characterization, and X-ray crystal structure of a one-dimensional calcium-based coordination polymer with strong blue fluorescent emission
Journal
Inorganic Chemistry Communications
Journal Volume
4
Journal Issue
8
Pages
430-433
Date Issued
2001
Author(s)
Abstract
The hydrothermal reaction of 4-cyanobenzoic acid with Ca(ClO4)2 · 6H2O yields the one-dimensional calcium-based coordination polymer [Ca(L)2(H2O)2]n 1 (where L = 4-cyanobenzoic acid) with strong blue fluorescent emission, and its solid-state structure has been characterized by X-ray single-crystal diffraction studies. Crystal data for 1: monoclinic, space group P2/n, a = 7.154 (2), b = 16.402 (3), c = 7.549 (2) Å; β = 115.83 (2)°; Z = 2; R = 0.0536 for 1410 independent reflections with I > 2α(1). © 2001 Elsevier Science B.V.
SDGs
Type
journal article