Dynamics and Kinetics of Metal Atoms in the Gas Phase
Resource
Journal of the Chinese Chemical Society 39 (6): 511-527
Journal
Journal of the Chinese Chemical Society
Journal Volume
39
Journal Issue
6
Pages
511-527
Date Issued
1992
Date
1992
Author(s)
林金全
Abstract
The review is divided into four sections. We first consider the varied behavior of K n2S and n2D states in their chemical reactivity and physical characterization. We review the effect of orbital alignment of an electronically excited metal atom on the cross section of energy transfer or chemical reaction, and report the technique of a single supersonic jet employed to measure this effect on the Ca spin‐changing collision. We discuss the effects of temperature and isotopic mass on the distribution of rotational quantum number of the product MgH to identify the reaction mechanism of Mg(1P1) + H2. The final concerns are the quantum yield, fine‐structure branching ratio and rate of collisional mixing for the K 2PJ doublets following photodissociation of KI at 193 nm. Copyright © 1992 The Chemical Society Located in Taipei & Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim, Germany
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Type
journal article
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