Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF
Journal
Dalton Transactions
Journal Volume
48
Journal Issue
6
Pages
1950-1954
Date Issued
2019
Author(s)
Lee, L.-W.
Kao, Y.-C.
Chung, M.-Y.
Chang, B.-C.
Lee, G.-H.
Wang, C.-M.
Liu, Y.-H.
Lee, S.-L.
Lu, K.-L.
Abstract
An SHG-active noncentrosymmetric (3,4)-connected Zn(ii)-organic framework, {[Zn2(4-abpt)(3,4-pydc)2]·2DMAc·3MeOH·H2O}n (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated ZnII ions with CuII ions while retaining the integrity of the network.
Type
journal article