Synthesis and Characterization of Oligo(2,7-biphenylenylene-(E)-vinylene)s: Conjugated Oligomers Containing AntiaromatIc 12-π Electron Units
Resource
Journal of the Chinese Chemical Society 44 (3): 211-224
Journal
Journal of the Chinese Chemical Society
Journal Volume
44
Journal Issue
3
Pages
211-224
Date Issued
1997
Date
1997
Author(s)
Abstract
The syntheses and the electionic properties of oligo(2,7-biphenylenylene-(E)-vinylene)s are reported. According to our spectral analysis, a limit of 2.5 ev for the peak band-gap of poly(2,7-biphenylenylene-(E)-vinylene)s is estimated. In addition, we discovered that oligo(2,7-biphenylenylene-(E)-vinylene)s are amphoteric and can be either oxidized or reduced electrochemically.
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journal article
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