Novel Thiotetraazapentalene Complexes from the Reaction of a Ruthenium Azide Complex with Alkyl Isothiocyanates
Resource
European Journal of Inorganic Chemistry 2004 (3): 459-462
Journal
European Journal of Inorganic Chemistry
Journal Issue
3
Pages
459-462
Date Issued
2004
Date
2004
Author(s)
Abstract
Abstract Reactions of the ruthenium azide complex 1 with alkyl isothiocyanates give novel ruthenium thiotetraazapentalenedithione complexes 3a − c containing a hypervalent sulfur atom. The ligand, bound through one sulfur atom, is derived from three isothiocyanate molecules and one nitrogen atom from an azide ion. The synthesis and structural determination of 3a − c , as well as a possible mechanism for their formation is described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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journal article
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