Palladium-catalyzed hydrosilylation of silyl-substituted butadienes
Resource
Heteroatom Chemistry 6 (1): 15-18
Journal
Heteroatom Chemistry
Pages
15-18
Date Issued
1995
Date
1995
Author(s)
Abstract
Abstract Palladium‐catalyzed hydrosilylation of silyl‐substituted butadienes 1 and 2 with MeSiCl 2 H has been investigated. Both steric effects and the presence of an aryl substituent affect the regiochemistry of the hydrosilylation reaction. Hydrosilylation of siloxanetethered bis‐dienes 9 exhibits high regio‐ and diastereoselectivity.
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Type
journal article
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