Chemistry of ruthenium azirinyl complexes and reversed regiospecificity of the carbonyl insertion reaction
Resource
Organometallics, Vol 20 3621-3623
Journal
Organometallics
Journal Volume
20
Journal Issue
17
Pages
3621-3623
Date Issued
2001
Author(s)
Abstract
The three azirinyl complexes (R = CN, CHCH2, Ph) are obtained from deprotonation of isonitrile complexes. For R = Ph, three isomers including 1H- and 2H-azirinyl complexes are observed at low temperature. Insertion of CO groups of acetone, aldehyde, ester, and amide into the azirinyl ligand follows regiospecificity opposite that in the photochemical-induced insertion of the organic azirine system.
SDGs
Type
journal article