https://scholars.lib.ntu.edu.tw/handle/123456789/314561
標題: | From vinylsilanes to organic/inorganic hybrid materials | 作者: | Luh, Tien-Yau TIEN-YAU LUH |
關鍵字: | Energy transfer; Light harvesting; Photovoltaic applications; Rhodium-catalyzed hydrosilylation; Stereoselective synthesis; Vinylsilanes | 公開日期: | 2005 | 卷: | 77 | 期: | 12 | 起(迄)頁: | 2083-2090 | 來源出版物: | Pure and Applied Chemistry | 摘要: | Alternating regioregular silylene-spaced divinylarene copolymers [(donor-SiMe2-)n=1-3-(acceptor-SiMe2)] are synthesized by rhodium-catalyzed hydrosilylation of bis-alkynes with bisvinylic silyl hydrides. Efficient intrachain energy transfer has been observed in these copolymers. The intensities of emission profiles depend on the relative ratio of donor-to-acceptor chromophores. The corresponding inorganic/organic hybrid materials are synthesized, and their photophysical properties are described. © 2005 IUPAC. |
URI: | http://www.scopus.com/inward/record.url?eid=2-s2.0-29244474363&partnerID=MN8TOARS http://scholars.lib.ntu.edu.tw/handle/123456789/314561 |
DOI: | 10.1351/pac200577122083 |
顯示於: | 化學系 |
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