Synthesis, characterization and crystal structures of 2,4-di(2- aminopyridine)-6-methypyrimidine (dapmp), [Cu(dapmp)Cl2] and [Cu(dapmp)(CH3COO)2] • H2O
Journal
Polyhedron
Journal Volume
24
Journal Issue
2
Pages
215-220
Date Issued
2005
Author(s)
Abstract
The new ligand dapmp (1) has been synthesized and the reactions of CuCl2 • 2H2O and Cu(CH3COO)2 • H2O with the new ligand in methanol afforded two crystalline polymorphic forms: [Cu(dapmp)Cl2] (2) and [Cu(dapmp)(CH 3COO)2] • H2O (3), where dapmp = 2,4-di(2-aminopyridine)-6-methylpyrimidine. Single crystal X-ray diffraction showed that (1) and (2) are each connected by hydrogen bonding to form a one-dimensional supermolecular compound and (3) is connected by hydrogen bonding to form a three-dimensional supermolecular compound. © 2004 Elsevier Ltd. All rights reserved.
Type
journal article