https://scholars.lib.ntu.edu.tw/handle/123456789/379898
標題: | Enhancement in open circuit voltage of organic photovoltaic devices through control of deposition rate of donor material | 作者: | Liu, S. W. Su, W. C. Lee, C. C. Lin, C. F. Cheng, C. W. Chou, C. C. Lee, J. H. Chen, C. T. JIUN-HAW LEE |
關鍵字: | Deposition rate; Molecular interaction; Morphology; Open-circuit voltage; Organic photovoltaic | 公開日期: | 2013 | 卷: | 109 | 起(迄)頁: | 280-287 | 來源出版物: | Solar Energy Materials and Solar Cells | 摘要: | In this paper, we demonstrate the effects of donor deposition rate on an organic photovoltaic device using bis(4-(N-(1-naphthyl)phenylamino)phenyl) fumaronitrile (NPAFN) as the donor. When the deposition rate of NPAFN increased from 0.03 to 0.5 nm/s, the performance of the device improved from 1.98% to 2.3% due to significant enhancement in the open-circuit voltage (VOC) from 0.81 to 0.97 V. With the aid of diode equation fitting, the improved V OC is attributed to the low saturation current caused by weak molecular interaction during the deposition of NPAFN at a high deposition rate. In order to understand the detail of the molecular interaction, the morphological property of NPAFN thin film with various deposition rates is investigated using atomic force microscopic images, which show the emergence of pinholes at low deposition rates as a result of strong molecular aggregation. Moreover, the weak molecular interaction is found to contribute to the low carrier mobility in NPAFN from the calculation of space charge limited current, leading to the considerably increased bulk resistance and reduced fill factor as the deposition rate increases. The detailed electrical properties of the NPAFN device were analyzed using impedance spectra. © 2012 Elsevier B.V. All rights reserved. |
URI: | http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000326858500040&KeyUID=WOS:000326858500040 http://scholars.lib.ntu.edu.tw/handle/123456789/379898 |
DOI: | 10.1016/j.solmat.2012.11.019 | SDG/關鍵字: | Atomic force; Bulk resistance; Fill factor; High deposition rates; Impedance spectrum; Microscopic image; Molecular aggregation; Morphological properties; Organic photovoltaic devices; Organic photovoltaics; Saturation current; Space charge limited currents; Electric properties; Molecular interactions; Molecular structure; Morphology; Naphthalene; Open circuit voltage; Photovoltaic effects; Deposition rates |
顯示於: | 光電工程學研究所 |
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