Os(II) phosphors with near-infrared emission induced by ligand-to-ligand charge transfer transition
Journal
Inorganic Chemistry
Journal Volume
53
Journal Issue
17
Pages
9366-9374
Date Issued
2014
Author(s)
Liao, J.-L.
Chi, Y.
Liu, S.-H.
Lee, G.-H.
Huang, H.-X.
Su, Y.-D.
Chang, C.-H.
Lin, J.-S.
Tseng, M.-R.
Abstract
Heating of Os3(CO)12 with 6 equiv of 2-(3-(trifluoromethyl)-1H-1,2,4-triazol-5-yl) pyridine (fptzH) in refluxing diethylene glycol monomethyl ether, followed by sequential treatment with stoichiometric Me3NO and addition of PPhMe2, afforded two isomeric mixtures of red-emitting [Os(fptz)2(PPhMe2) 2] (1T and 1C), for which the notations T and C stand for the trans and cis-oriented fptz chelates, respectively. Alternatively, preparation of Os(II) complex using a 1:1 mixture of 5,5′-di(trifluoromethyl)-3,3′- di-1,2,4-triazole (dttzH2) and 2,2′-bipyridine (bpy), instead of fptzH, gave isolation of a mononuclear Os(II) complex [Os(bpy)(dttz)(CO) 2] (2) in moderate yield. Replacement of CO with PPhMe2 on 2 afforded near-infrared (NIR)-emitting Os(II) complex [Os(bpy)(dttz) (PPhMe2)2] (3). The single-crystal X-ray structural analyses were executed on 1C, 2, and 3 to reveal the structural influence imposed by the various chelates. The photophysical and electrochemical properties were measured and discussed using the results of density functional theory (DFT) and time-dependent DFT calculations. Complex 3 is selected as the dopant to probe its electroluminescent properties by fabrication of the NIR emitting organic light-emitting diodes. © 2014 American Chemical Society.
SDGs
Type
journal article