https://scholars.lib.ntu.edu.tw/handle/123456789/408997
標題: | A dimensionally stable and fast-discharging graphite-silicon composite Li-ion battery anode enabled by electrostatically self-assembled multifunctional polymer-blend coating | 作者: | Li F.-S. Wu Y.-S. Chou J. Wu N.-L. |
公開日期: | 2015 | 卷: | 51 | 期: | 40 | 起(迄)頁: | 8429-8431 | 來源出版物: | Chemical Communications | 摘要: | A high-performance graphite-Si composite anode for Li-ion batteries containing Si nanoparticles (NPs) attached onto graphite microparticles was synthesized by adopting a polymer-blend of poly(diallyl dimethyl-ammonium chloride) and poly(sodium 4-styrenesulfonate). The polymer-blend enabled uniform distribution of Si NPs during synthesis and served as a robust artificial solid-electrolyte interphase that substantially enhanced the cycle stability and rate performance of the composite electrode. The electrode exhibited a specific capacity of 450 mA h g-1, 96% capacity retention at a 10 C-rate, 95% retention after 200 cycles, and the same electrode expansion behavior as a pristine graphite electrode. This journal is ? The Royal Society of Chemistry 2015. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/408997 | ISSN: | 13597345 | DOI: | 10.1039/c4cc09825k |
顯示於: | 化學工程學系 |
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