https://scholars.lib.ntu.edu.tw/handle/123456789/409871
標題: | Partially fluorinated poly-p-xylylenes synthesized by CVD polymerization | 作者: | Elkasabi Y. Nandivada H. Chen H.-Y. Bhaskar S. D'Arcy J. Bondarenko L. Lahann J. |
關鍵字: | Fluorinated polymers;Poly-p-xylylenes;Superhydrophobic surfaces;Surface engineering | 公開日期: | 2009 | 卷: | 15 | 期: | 4-6 | 起(迄)頁: | 142-149 | 來源出版物: | Chemical Vapor Deposition | 摘要: | This paper describes partially fluorinated poly-p-xylylenes prepared by CVD polymerization. The synthesis, characterization, and surface modification of two partially fluorinated polymer coatings, namely poly(4,12-dibromo-1,1,9,9- tetrafluoro-pxylylene) (2) and poly(4-heptadecafluorononanoyl-p-xylylene-co-p- xylylene) (4), is described. Polymer 2 is synthesized from 4,12-dibromo-1,1,9,9- tetrafluoro[2.2]paracyclophane (1), which is fluorinated at the aliphatic bridge, while 4-heptadecafluorononanoyl[ 2.2]paracyclophane (3), which contains a perfluorinated keto group at the aromatic ring, is used to synthesize polymer 4. Furthermore, the keto-functionalized polymer 4 introduces both extreme hydrophobicity and surface reactivity towards hydrazide-containing ligands. ?2009 WILEY-VCH Verlag GmbH &Co. KGaA, Weinheim. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/409871 | ISSN: | 09481907 | DOI: | 10.1002/cvde.200806749 |
顯示於: | 化學工程學系 |
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