|Title:||Simple sonochemical synthesis of lanthanum tungstate (La<inf>2</inf>(WO<inf>4</inf>)<inf>3</inf>) nanoparticles as an enhanced electrocatalyst for the selective electrochemical determination of anti-scald-inhibitor diphenylamine||Authors:||Gnanaprakasam, Periyasami
Chen, Shen Ming
Mangalaraja, Ramalinga Viswanathan
|Keywords:||(La (WO ) ) 2 4 3 | Anti-scald-inhibitor | Diphenylamine | Electrocatalyst | Nanoparticles | Sonochemical||Issue Date:||1-Nov-2019||Journal Volume:||58||Source:||Ultrasonics Sonochemistry||Abstract:||
© 2019 Elsevier B.V. In this work, lanthanum tungstate (La2(WO4)3) nanoparticles (NPs) were synthesized by facile sonochemical method (elmasonic P, under-sonication 37/100 kHz, ~60 W energy) and utilized as an electrode material for the selective and sensitive electrochemical determination of anti-scald inhibitor diphenylamine (DPA). The synthesized La2(WO4)3 NPs were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), energy dispersive x-ray spectroscopy (EDAX), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS) analyses. The results revealed that the sonochemically synthesized La2(WO4)3 nanoparticles were with high crystallinity and uniformly distributed nanoparticles like structure. The as-prepared lanthanum tungstate NPs exhibited an excellent electrocatalytic behavior for DPA determination with the lowest detection limit of 0.0024 µM, wide linear range response of 0.01–58.06 µM and a remarkable sensitivity of 1.021 µA µM−1 cm−2. Furthermore, La2(WO4)3 NPs showed a good recovery to DPA in apple juice sample. Besides, the electrochemical mechanism of the DPA oxidation reaction was provided in detail.
|Appears in Collections:||政治學系|
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