https://scholars.lib.ntu.edu.tw/handle/123456789/581555
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Matsagar B.M | en_US |
dc.contributor.author | Hsu C.-Y | en_US |
dc.contributor.author | Chen S.S | en_US |
dc.contributor.author | Ahamad T | en_US |
dc.contributor.author | Alshehri S.M | en_US |
dc.contributor.author | Tsang D.C.W | en_US |
dc.contributor.author | Wu K.C.-W. | en_US |
dc.contributor.author | KEVIN CHIA-WEN WU | en_US |
dc.creator | Matsagar B.M;Hsu C.-Y;Chen S.S;Ahamad T;Alshehri S.M;Tsang D.C.W;Wu K.C.-W. | - |
dc.date.accessioned | 2021-09-02T02:29:07Z | - |
dc.date.available | 2021-09-02T02:29:07Z | - |
dc.date.issued | 2019 | - |
dc.identifier.issn | 23984902 | - |
dc.identifier.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85076959867&doi=10.1039%2fc9se00681h&partnerID=40&md5=a59b5823230537924b5fadfc6b3d7831 | - |
dc.identifier.uri | https://scholars.lib.ntu.edu.tw/handle/123456789/581555 | - |
dc.description.abstract | We describe the selective hydrogenation of furfural (FAL) into tetrahydrofurfuryl alcohol (THFA) under mild conditions (30 °C) in aqueous media using an Rh-loaded carbon (Rh/C) catalyst in a one-pot fashion. In FAL hydrogenation, the Rh/C catalyst showed a high THFA yield (92%) with 93% selectivity in aqueous media within 12 h, whereas the use of a dimethylacetamide (DMA) solvent system resulted in a 95% THFA yield within 32 h at 30 °C. The study of the effect of the solvent on FAL hydrogenation reveals that polar solvents showed higher THFA yields than a toluene solvent. The Rh/C catalyst used in this study exhibited higher activity compared to Ru/C, Pd/C, Ni/C derived from Ni-based metal-organic framework (Ni-MOF), and Ni-loaded carbon black (Ni/CB) catalysts in FAL-to-THFA hydrogenation. The Rh/C catalyst is characterized in detail using various characterization techniques such as TEM, XRD, N2-adsorption-desorption, XPS, and ICP-OES to understand its physicochemical properties. The Rh/C catalyst shows similar high THFA yields in the recycling experiment of FAL hydrogenation under ambient conditions. ? 2019 The Royal Society of Chemistry. | - |
dc.relation.ispartof | Sustainable Energy and Fuels | - |
dc.subject | Aldehydes; Carbon black; Furfural; Hydrogenation; Organic solvents; Organometallics; Physicochemical properties; Ambient conditions; Carbon catalysts; Characterization techniques; Dimethylacetamide; Metal organic framework; Recycling experiments; Selective hydrogenation; Tetrahydrofurfuryl alcohols; Catalyst selectivity; alcohol; aqueous solution; catalyst; physicochemical property; recycling; solvent; toluene | - |
dc.title | Selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over a Rh-loaded carbon catalyst in aqueous solution under mild conditions | en_US |
dc.type | journal article | en |
dc.identifier.doi | 10.1039/c9se00681h | - |
dc.relation.pages | 293-301 | - |
dc.relation.journalvolume | 4 | - |
dc.relation.journalissue | 1 | - |
item.fulltext | no fulltext | - |
item.openairetype | journal article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | Chemical Engineering | - |
crisitem.author.orcid | 0000-0003-0590-1396 | - |
crisitem.author.parentorg | College of Engineering | - |
顯示於: | 化學工程學系 |
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