https://scholars.lib.ntu.edu.tw/handle/123456789/606866
Title: | [Mes-B-TMP]+borinium cation initiated cyanosilylation and catalysed hydrosilylation of ketones and aldehydes | Authors: | Chen P.-H Hsu C.-P Tseng H.-C Liu Y.-H CHING-WEN CHIU |
Keywords: | Aldehydes;Ketones;Positive ions;Catalyse;Cyanosilylation;Divergents;Hydrosilylations;Methyl migrations;Silylium ions;Hydrosilylation | Issue Date: | 2021 | Journal Volume: | 57 | Journal Issue: | 100 | Start page/Pages: | 13732-13735 | Source: | Chemical Communications | Abstract: | Two aryl amino borinium cations derived from Cl(Mes)B-NR2(NR2= TMP, HMDS) faced divergent outcomes. As the HMDS-substituted one underwent methyl migration from silicon to boron transforming the putative borinium ion to a silylium ion, [Mes-B-TMP]+can initiate cyanosilylation and catalyse hydrosilylation of ketones and aldehydes. ? The Royal Society of Chemistry 2021. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85121576742&doi=10.1039%2fd1cc06319g&partnerID=40&md5=2b2ee76d010ea36fb73f02c75120643e https://scholars.lib.ntu.edu.tw/handle/123456789/606866 |
ISSN: | 13597345 | DOI: | 10.1039/d1cc06319g |
Appears in Collections: | 化學系 |
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